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In your server configuration document, there is a field for setting the relay host for messages leaving the Internet domain. If you put a comma separated value in there (can be IP addresses or hostnames), the SMTP router will try all the outbound relay hosts you specify when trying to send outbound SMTP mail.

Notes R4
Notes/Domino 4.5
Notes/Domino 4.6
Notes/Domino R5
Notes/Domino 6
Notes/Domino 6.5
Notes/Domino 7